The analysis of silicate ad carbonate rocks

Govt. Print. Off., 1907 - 200 Seiten

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Seite 153 - CO2 with which to sweep out the apparatus before and after the experiment and for a slow current during its continuance. The results are very accurate and the determination can be quickly carried out. The manipulations are as follows...
Seite 160 - It is an exceptional case when there is exact agreement between the weight of fluoride and sulphate, and with the small amounts usually met in rocks the error may be an appreciable one in percentage of fluorine, though of no great significance otherwise.
Seite 111 - Almost invariably a small precipitate soon shows itself, which, if fine grained and nonadherent to the glass, may be regarded as pure calcium oxalate; otherwise it contains, or may largely consist of, magnesium oxalate. It is in that case to be collected, ignited, redissolved, and reprecipitated. Its final weight, averaging perhaps one-half milligram, is to be added to that of the lime already found and subtracted as tricalcium phosphate (not pyrophosphate) from that of the magnesium pyrophosphate,...
Seite 167 - OF SOLUBLE SILICA. Very often in treatment by acids silica is separated in gelatinous or granular form mixed with the unattacked minerals, and it becomes necessary to remove or estimate this silica, or else to discriminate between soluble and insoluble silica already existing together. Usually a boiling solution of sodium carbonate has been employed for this purpose, though the caustic alkalies have found advocates. G. Lunge and 0. Millberg...
Seite 57 - ... where again, of course, the finer the sample is ground for the analysis the greater the possible error from this cause. It may be that a part and occasionally all of the moisture...
Seite 163 - Most of the hydrogen sulphide would be expelled before any such action could take place and probably before the ferric salts were largely attacked, but of course the small proportion of sulphur set free as such from pyrrhotite would escape estimation and introduce further uncertainty. In general, it would be safe enough to assume the composition Fe7S8 for pyrrhotite.
Seite 121 - Soc., vol. 49, 1886, pp. 149, 481. the titanium, and then a few drops of a soluble orthophosphate solution. The flask is set aside in the cold for twenty-four to forty-eight hours. If the color bleaches after a time, more hydrogen peroxide should be added. Under these circumstances the zirconium is thrown out as phosphate and collects as a flocculent precipitate, which at this stage is not always pure. (For the treatment of the nltrate see " Rareearth metals,
Seite 64 - ... description, shows it in a modified form, which differs from the original forms of Gooch in that the tubes for connecting with both the drying and absorption vessels are constructed wholly of platinum instead of lead glass.
Seite 133 - ... and petrographer, than the determination of iron in ferrous condition. The sealed-tube or Mitscherlich method with sulphuric acid, for a long time the only available one, is in theory perfect, since complete exclusion of oxygen is easily attainable. Its earliest recognized defect lies in the inability to secure always complete decomposition of the iron-bearing minerals, and even to ascertain, oftentimes, whether or not the decomposition has been complete. The addition of hydrofluoric acid to...
Seite 193 - ... transferred to an evaporating dish, preferably of platinum for the sake of celerity in evaporation, moistened with enough water to prevent lumping, and 5 to 10 cc of strong HC1 added and digested with the aid of gentle heat and agitation until solution is complete. Solution may be aided by light pressure with the flattened end of a glass rod.* The Solution is then evaporated to dryness, as far as this may be possible on the bath.

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